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Chlorine monofluoride
・ Chlorine monoxide
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Chlorine monofluoride : ウィキペディア英語版
Chlorine monofluoride

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Chlorine monofluoride is a volatile interhalogen compound with the chemical formula ClF. It is a colourless gas at room temperature and is stable even at high temperatures. When cooled to −100 °C, ClF condenses as a pale yellow liquid. Many of its properties are intermediate between its parent halogens, Cl2 and F2.
==Reactivity==
Chlorine monofluoride is a versatile fluorinating agent, converting metals and non-metals to their fluorides and releasing Cl2 in the process. For example, it converts tungsten to tungsten hexafluoride and selenium to selenium tetrafluoride:
:W + 6 ClF → WF6 + 3 Cl2
:Se + 4 ClF → SeF4 + 2 Cl2
ClF can also chlorofluorinate compounds, either by addition across a multiple bond or via oxidation. For example, it adds fluorine and chlorine across the triple bond of carbon monoxide:
:CO + ClF →

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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